You can do this in Windows too, useful if you want tiny executables that use minimum resources.
I wrote this little systemwide mute utility for Windows that way, annoying to be missing some parts of the CRT but not bad, code here: https://github.com/pablocastro/minimute
You have your usual Win32 API functions found in libraries like Kernel32, User32, and GDI32, but since after Windows XP, those don't actually make system calls. The actual system calls are found in NTDLL and Win32U. Lots of functions you can import, and they're basically one instruction long. Just SYSENTER for the native version, or a switch back to 64-bit mode for a WOW64 DLL. The names of the function always begin with Nt, like NtCreateFile. There's a corresponding Kernel mode call that starts with Zw instead, so in Kernel mode you have ZwCreateFile.
But the system call numbers used with SYSENTER are indeed reordered every time there's a major version change to Windows, so you just call into NTDLL or Win32U instead if you want to directly make a system call.
Windows isn’t quite like Linux in that typically apps don’t make syscalls directly. Maybe you could say what’s in ntdll is the system call contract, but in practice you call the subsystem specific API, typically the Win32 API, which is huge compared to the Linux syscall list because it includes all sorts of things like UI, COM (!), etc.
The project has some of the properties discussed above such as not having a typical main() (or winmain), because there’s no CRT to call it.
I wrote this little systemwide mute utility for Windows that way, annoying to be missing some parts of the CRT but not bad, code here: https://github.com/pablocastro/minimute