I'm not sure I understand your question exactly, but I am fairly certain that not all quintic fields can be solved by the combination of (1) radicals, i.e. taking roots of x^n - 1, and (2) taking roots of x^5 - x - 1. I don't have a proof in mind at the moment, but I speculate it's not too terribly difficult to prove.
If I'm correct, then the proof would almost certainly use Galois theory!
If I'm correct, then the proof would almost certainly use Galois theory!