I'm using EF Core with SQL Server and PostgreSQL for two different production projects; it works like a charm, and the performance is great.
All recent projects in my company are PostgreSQL based (> 2000 production applications), and we have far fewer troubles with PostgreSQL than with Oracle, not to mention the licensing.
I have used it in multiple projects and it works great. The Npgsql.EntityFrameworkCore.PostgreSQL provider is always quickly updated when new versions of EF Core are shipped, and its primary maintainer @roji is also extremely talented and responsive. All around has been a pleasure to work with!
I'm managing two medium sized projects on that stack, using both EF core and Dapper. I'm about to switch a third over from Oracle because I'm so tired of all the issues with Oracle.