The biggest opportunity I can see here is Cars as a Service. Basically an automated taxi service you pay $50/month for to use a car whenever you want. You fire up the caas app,order a car, and the nearest one comes and grabs you. The best part: not location dependent. Your membership is good in any city (heck, even any country). It would be the end of taxis and even public transportation.
I imagine this is already possible but with people as drivers instead of machines, you just need some badass coordination in your cellphone app service.
Possible, yes, but you have to both buy the cars and pay the drivers, one of the reasons taxis are so expensive (the other being licenses running in the hundreds of thousands of dollars). If we project 5 years down the road to a time when gas prices are even higher, electric vehicles are cheaper and more reliable, and the technology is ready for prime time, I could easily see cars as a service working.