Well... dead planets (that harbor no life) are lower entropy than living planets as their surfaces change much less over time. Fewer possible microstates = low entropy.
Hence, if you take a complex biochemical system and reduce it to <100 piles of atoms of specific elements, this is a lower entropy state. Mass extinctions, collapse of civilizations, that does lead to a 'more stable and ordered' state.
[1] https://en.wikipedia.org/wiki/Entropy